Heat

In physics, heat, symbolized by Q, is energy transferred from one body or system to another due to a difference in temperature. more...

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In thermodynamics, the quantity TdS is used as a representative measure of heat, which is the absolute temperature of an object multiplied by the differential quantity of a system's entropy measured at the boundary of the object. Heat can flow spontaneously from an object with a high temperature to an object with a lower temperature. The transfer of heat from one object to another object with an equal or higher temperature can happen only with the aid of a heat pump. High temperature bodies, which often result in high rates of heat transfer, can be created by chemical reactions (such as burning), nuclear reactions (such as fusion taking place inside the Sun), electromagnetic dissipation (as in electric stoves), or mechanical dissipation (such as friction). Heat can be transferred between objects by radiation, conduction and convection. Temperature is used as a measure of the internal energy or enthalpy, that is the level of elementary motion giving rise to heat transfer. Heat can only be transferred between objects, or areas within an object, with different temperatures (as given by the zeroth law of thermodynamics), and then, in the absence of work, only in the direction of the colder body (as per the second law of thermodynamics). The temperature and phase of a substance subject to heat transfer are determined by latent heat and heat capacity. A related term is thermal energy, loosely defined as the energy of a body that increases with its temperature.

Overview

The first law of thermodynamics states that the energy of a closed system is conserved. Therefore, to change the energy of a system, energy must be transferred to or from the system. Heat and work are the only two mechanisms by which energy can be transferred to or from a control mass. Heat is the transfer of energy caused by the temperature difference. The unit for the amount of energy transferred by heat in the International System of Units SI is the joule (J), though the British Thermal Unit and the calorie are still occasionally used in the United States. The unit for the rate of heat transfer is the watt (W = J/s).

Heat transfer is a path function (process quantity), as opposed to a point function (state quantity). Heat flows between systems that are not in thermal equilibrium with each other; it spontaneously flows from the areas of high temperature to areas of low temperature. When two bodies of different temperature come into thermal contact, they will exchange internal energy until their temperatures are equalized; that is, until they reach thermal equilibrium. The adjective hot is used as a relative term to compare the object’s temperature to that of the surroundings (or that of the person using the term). The term heat is used to describe the flow of energy. In the absence of work interactions, the heat that is transferred to an object ends up getting stored in the object in the form of internal energy.

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